Synthesis and application of phenylcarbamodithioate compound for steel protection

Phenyldithiocarbamate compound has been synthesized and studied as corrosion inhibitor for steel. Dithiocarbamate (DTC) compounds with linear alkyl groups are good inhibitors, but their stability is quite low in acidic solutions. It should be noted that long-term stability is important for practical applications, in order to avoid excess use of chemicals. So, we have synthesized phenyl substituted DTC which offers strong inhibition efficiency and extra stability. This new inhibitor is chemically adsorbed on steel through its DTC group, while the aromatic ring provides extra stability and long-term efficiency. For the assessment of corrosion kinetics, we have utilized potentiodynamic and ac impedance studies; also solution assay analysis was realized with atomic absorption spectroscopy. It was revealed that inhibitor exhibits remarkably high efficiency, even under elevated temperature conditions. At 55 °C temperature conditions, i_corr value decreased from 5050 to 154 μA cm^?2, with the addition of 500 ppm inhibitor. The long-term stability of inhibitor was also tested and 85.93% efficiency was obtained after three days of exposure period for 500 ppm concentration.     

Optimization of spray drying process of Sargassum muticum color extract

ABSTRACT

Sargassum muticum is categorized as a brown seaweed species which has been used as a dye fabric colorant in certain regions of Asia. The brown extracts of S. muticum also have antioxidant properties, which could enhance the color and nutrients in food products. However, the color extract is unstable, and also limits the application. This study was performed to encapsulate the color extract with maltodextrin and stabilize the color extract by spray drying technique using combinations of various levels of inlet temperature and feed flow rate. Initially, S. muticum powder was analyzed for moisture content, water activity, solubility, and color properties for optimization purposes. This study showed that the optimum inlet temperature and feed flow rate of the spray drying process to produce good-quality, stable, and acceptable powder properties were at 140°C and 3?rpm, respectively, with 4% of maltodextrin. Then, the powder was analyzed for density, compressibility index, hygroscopicity, particle size, and antioxidant properties. This study represents an interesting food additive to be incorporated in functional food due to the attractive brown colorant and the presence of antioxidants.     

Microbial fuel cell-based sensor for Enterobacter sp. KBH6958 activity monitoring during hydrogen production: the effects of pH and glucose concentration

Journal of Applied Electrochemistry - A microbial fuel cell (MFC) is an electricity-generating device utilising electrochemically active microorganisms as biocatalysts. Using MFC as a biosensor to...     

Misalignment tolerance analysis of free-space optical interconnects via statistical methods

System-level packaging is one of the critical issues that need to be addressed for free space optical interconnections (FSOI) to become useful in desktop systems. The performance of FSOI, e.g., in terms of system bit-error rate, is greatly affected by misalignments in the optical system. Therefore tolerancing, i.e., the ability to analyze and predict the effects of misalignments in the system, is of prime importance to system designers. We introduce an approach in which we study the effects of optical misalignments and other tolerance factors using statistical methods. We use Monte Carlo simulations, design of the experiments, and regression techniques to fit a polynomial equation that expresses the relationship between the system performance and the tolerance factors. This prediction model can be used for design, cost optimization, and quality control purposes. In addition, we perform a sensitivity analysis to determine those tolerance variables that have the greatest effect on system performance.     

Synthesis of finite state machines for improved state verification

Finite State Machines (FSMs) are used in diverse areas to model hardware and software systems. Verification of FSMs is essential to ensure reliability of systems. To verify that a machine is in an expected state in testing, Unique Input/Output (UIO) sequences are used. The aforementioned testing methodology requires that each state in the FSM has an UIO. However, it is possible for a given machine that few or even none of its states have an UIO sequence. This paper presents a guided heuristic algorithm for synthesizing FSMs such that each state has an UIO sequence. The states of an FSM with identical I/O labels on transitions are grouped in order to identify the states which do not possess UIO sequence. The transitions are then augmented by adding extra output terminals incrementally so that new UIO sequences are created for the states. A greedy approach is used to optimize the number of added outputs. Initially, the transitions which lead to state convergence (i.e., transitions with identical input/output labels taking a set of states to the same next state) and constrained self-loop (i.e., transitions taking a set of states either to itself or leads to state convergence) are identified since a state with only these transitions will never have a UIO sequence. Extra output terminals are added to the FSM which are used only while testing and the augmented output labels make sure that the states are neither convergent nor has constrained self-loop, thereby ensuring UIO sequence. The proposed algorithm, referred to as AUGP, was tested with a large number of FSMs including the Microelectronics Center of North Carolina (MCNC) FSM benchmarks. The augmented state transition table was used as input to a UIO computation algorithm (developed by the same authors [Ahmad I, et al. IEE Proc Comput Digital Tech 2004;151(2):131]) to check the performance of the augmentation algorithm and the tested FSMs were found to possess UIO sequence for all states.     

Productions and monomer compositions of exopolysaccharides by Lactobacillus delbrueckii subsp. bulgaricus and Streptococcus thermophilus strains isolated from traditional home-made yoghurts and raw milk

In this study, a total of forty‐five strains of lactobacilli and streptococci were determined exopolysaccharide (EPS) production in skim milk and Man Rogosa and Sharpe (MRS)/M17 medium, viscosity and proteolytic activity. The exopolysaccharide production by lactobacilli strains during growth in MRS medium was twenty‐one to 211 mg L^?1, while in skim milk was to thirty‐six to 315 mg L^?1. The EPS production by streptococci strains during growth in M17 medium was sixteen to 114 mg L^?1, while in skim milk was to twenty‐four to 140 mg L^?1. The EPS production of strains was lower in MRS/M17 medium than skim milk. Results showed that it was not clear correlation between the viscosity and EPS production of some strains. All strains were shown proteolytic activity. Positive correlations between exopolysaccharide production and proteolytic activity in skim milk were found some strains of Lactobacillus delbrueckii subsp. bulgaricus and Streptococcus thermophilus. These results indicated that the high exocellular protease‐producing strains can produce high EPS in skim milk. The monomer compositions of the EPSs formed by selected five strains were analysed. Mannose dominated (99–100%) on the EPS produced by L. delbrueckii subsp. bulgaricus and S. thermophilusstrains (except L. delbrueckii subsp. bulgaricus 22) in skim milk and MRS/M17 medium. Besides, the EPSs of strains in skim milk contained small amount of lactose.     

Evaluation of counterions for electrospray ionization mass spectral analysis of a highly sulfated carbohydrate,sucrose octasulfate

A systematic approach was used to evaluate the electrospray ionization mass spectral (ESI-MS) analysis of sucrose octasulfate (SOS), an important pharmaceutical agent. SOS represents a model for other suffated carbohydrates, such as heparin and glycosaminoglycan-derived oligosaccharides that also are highly sulfated and pose difficult analytical problems. A survey of ammonium counterions showed that 1 degree, 2 degrees, and 3 degrees ammonium salts of SOS gave substantial fragmentation as a result of sulfate loss. In contrast, quaternary ammonium and phosphonium salts gave excellent ESI spectra, particularly in the positive ion mode. This represents the first report of the ESI-MS analysis of sulfated carbohydrates in the positive ion mode.     

Applied Genetic Algorithm for Solving Rich VRP

In this article, we present a study of the effectiveness of a genetic algorithm (GA) to solve a combinatorial problem, that is, a vehicle routing problem (VRP). We propose a new selection method, called “rank and select,” based on selection rate, and we compare it with roulette wheel selection. In this article, we use two types of crossover method and two types of mutation method. These are applied for comparing the best fitness at the end of a generation. The problem solved in this study is how to generate feasible route combinations for a rich VRP and meet all the requirements with an optimum solution. Initial test results show that the route produced by the GA was effectively used for solving rich VRP and especially for a large number of customers, depots, and vehicles. Fuel consumption by proposed routes was lower by about 20.38% compared to that of an existing route.     

Cell Culture on MEMS Platforms: A Review

Microfabricated systems provide an excellent platform for the culture of cells, and are an extremely useful tool for the investigation of cellular responses to various stimuli. Advantages offered over traditional methods include cost-effectiveness, controllability, low volume, high resolution, and sensitivity. Both biocompatible and bio-incompatible materials have been developed for use in these applications. Biocompatible materials such as PMMA or PLGA can be used directly for cell culture. However, for bio-incompatible materials such as silicon or PDMS, additional steps need to be taken to render these materials more suitable for cell adhesion and maintenance. This review describes multiple surface modification strategies to improve the biocompatibility of MEMS materials. Basic concepts of cell-biomaterial interactions, such as protein adsorption and cell adhesion are covered. Finally, the applications of these MEMS materials in Tissue Engineering are presented.